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Lots of energy needed to break the strong electrostatic attraction between cation and delocalised electrons.

Delocalised electrons can flow/move and carry a charge

The layers can slide past each other, but it doesn’t break the strong electrostatic attraction between cation and delocalised electron.

Properties of Metals:Properties of non-metals:
Good conductors of heat & electricityPoor conductors of heat & electricity
StrongBrittle (Break easily)
Malleable (Can be hammered into shape)Low Melting Points & Boiling Points
Ductile (Can be stretched into wires)Low Density
High Melting Points & Boiling Points

A polymer is a long chain of smaller molecules called monomers.

These are examples of simple covalent compounds and have low melting points and cannot conduct electricity.

An example of this is ethene – which has the formula C2H4:

When the double bond is broken, many ethene molecules will join together to make poly(ethene):

2D Models:

Advantages:

  • Simple.
  • Shows the atoms involved.
  • Shows how the atoms are connected.

Disadvantages:

  • Doesn’t show the shape of the substance.
  • Doesn’t show the size of the substance.

Dot and Cross:

Advantages:

  • Shows the electron arrangement.
  • Shows how substances are formed.
  • Shows where the electrons are from.

Disadvantages:

  • Doesn’t show the size of the substance.
  • Doesn’t show you how the ions are arranged.

3D Models:

Advantages:

  • Shows the arrangement of the ions.
  • Shows the shape of the substance

Disadvantages:

  • Only shows the outer layer of the substance.
  • Doesn’t show the correct size of the atoms.

Ball and Stick:

Advantages:

  • Shows the shape of the lattice/structure in 3D.
  • Show the atoms and their arrangement.
  • More realistic than 2D drawings.

Disadvantages:

  • Misleading – the gaps shown are not really there – that’s where the electrons are.
  • Doesn’t show the correct size of the atoms.

Example: Look at the table below – can you name the type of bonding for each?

  • Substance A is simple covalent because it has a low boiling point. (It is the only type of bonding with a low boiling point!!)
  • Substance B is giant covalent because it has a high melting point (ionic, giant covalent and metallic), is made of only non-metals, and doesn’t conduct electricity.
  • Substance C is ionic because it conducts electricity when liquid, but not when solid. (It is the only type of substance that only conducts when liquid/molten/dissolved).
  • Substance D is metallic because only metals conduct electricity when both liquid and solid.

There are lots of ways to find out if a substance is ionic, covalent or metallic. Here are a few:

  • Heat the substance. If it melts quickly it must be simple covalent.
  • Add it to a circuit. Does the bulb light up as a solid? If so it is metallic (or graphite – you can check if it’s shiny in that case!)
  • If it doesn’t conduct, dissolve and try again. If, when dissolved/melted, it does now conduct, it must be an ionic substance.

Ionic

Property 1:

High Melting Point

Explanation:

Lots of energy is needed to break the strong electrostatic attraction between the cations and anions.

Property 2:

Only conduct electricity when molten

Explanation:

When solid, the ions are not free to move. When liquid/molten the ions are free to move.

Simple Molecular

Property 1:

Low Melting Point

Explanation:

Not much energy to break the weak intermolecular forces.

Property 2:

Don’t conduct electricity

Explanation:

No spare/delocalised electrons to pass on a charge.

Giant Covalent

Property 1:

High Melting Point

Explanation:

Lots of energy is needed to break the strong covalent bonds.

Property 2:

Don’t conduct electricity (with exceptions)

Explanation:

No spare/delocalised electrons can flow to pass on a charge.

Exceptions: nanotubes/graphite/graphene: Delocalised electrons can flow and pass on a charge.

Metallic

Property 1:

High Melting Point

Explanation:

Lots of energy is needed to break the strong electrostatic attraction between the cations and delocalised electrons.

Property 2:

Do Conduct Electricity

Explanation:

Delocalised electrons can flow/move and pass on a charge.